期刊
ORGANOMETALLICS
卷 32, 期 6, 页码 1579-1582出版社
AMER CHEMICAL SOC
DOI: 10.1021/om301267c
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资金
- NSF through the CCI Center for Enabling New Technologies through Catalysis (CENTC) [CHE-1205189, CHE-0650456]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1205189] Funding Source: National Science Foundation
Stoichiometric alkane dehydrogenation utilizing an Ir-III pincer complex, ((dm)Phebox)Ir(OAc)(2)(OH2) (1a), has been described. The reaction between la and octane resulted in quantitative formation of ((dm)Phebox)Ir(OAc)(H) (3a) and octene. At early reaction times 1-octene is the major product, indicative of terminal C-H activation by la. In contrast to prior reports of alkane dehydrogenation with Ir, C-H bond activation occurs at Ir-III and the dehydrogenation is not inhibited by nitrogen, olefin, or water.
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