4.5 Article

Borane-Catalyzed Si-H Activation Routes to Polysilanes Containing Thiolato Side Chains

期刊

ORGANOMETALLICS
卷 32, 期 6, 页码 1575-1578

出版社

AMER CHEMICAL SOC
DOI: 10.1021/om301246z

关键词

-

资金

  1. University of Victoria
  2. NSERC of Canada

向作者/读者索取更多资源

Dehydrocoupling and hydrosilation reactions of the Si-H bonds in poly(phenylsilane) catalyzed by B(C6F5)(3) allow the preparation of new polymers containing both Si-H and Si-SR side chains. This postpolymerization modification takes place without any observable competing Si-Si bond cleavage, unlike other Lewis acid, transition-metal, or radical mediated routes. The -SR-functionalized polymers have been characterized by GPC, IR, UV-vis, elemental analysis, and H-1, C-13, and Si-29 NMR.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.5
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据