Terminal 1,2-dialkynylarenes undergo an unexpected cyclization hydroarylation reaction toward naphthalene derivatives in benzene as the solvent. The regioselectivity of the reaction can be controlled by careful catalyst tuning. Also, the preparation of a bench-stable cationic amine complex or simple heterogenization of the catalyst on neutral aluminum oxide, which enables efficient catalyst recycling, was possible. Intensive mechanistic investigations were undertaken, giving new insights into the so-far underestimated role of acetylides in gold chemistry. The gold plays a fascinating dual role serving to both catalyze the reaction and activate the substrate by Au-C-sigma bond formation. Evidence of gem-diaurated compounds playing an important part for gold catalysis is also reported.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据