4.5 Article

Synthesis, Structure, and Properties of a Stable 1,2-Dibromodialumane(4) Bearing a Bulky Aryl Substituent

期刊

ORGANOMETALLICS
卷 31, 期 9, 页码 3806-3809

出版社

AMER CHEMICAL SOC
DOI: 10.1021/om300237q

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资金

  1. Ministry of Education, Culture, Sports, Science and Technology of Japan [22350017, 21750037, B09]
  2. Grants-in-Aid for Scientific Research [21750037, 22350017, 24550048] Funding Source: KAKEN

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The stable 1,2-dibromodialumane(4) Bbp(Br)Al-Al(Br)Bbp (1; Bbp = 2,6-bis[bis(trimethylsily)methyl]phenyl) was synthesized by the reduction of the corresponding dibromoalumane etherate BbpAlBr(2)center dot OEt2 (2). The structure and properties of 1 have been elucidated on the basis of the analyses of spectroscopic and crystallographic data and are supported by DFT calculations.

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