期刊
ORGANOMETALLICS
卷 31, 期 8, 页码 2949-2952出版社
AMER CHEMICAL SOC
DOI: 10.1021/om300127g
关键词
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资金
- NSERC of Canada
- Canada Council of the Arts
- NSERC
- Alberta Innovates-Technology Futures
The synthesis of two members of a new PCP pincer ligand family and their complexation with iridium has been developed. Double C-H activation results in a ligand anchored by a carbene donor; hydrogen reversibly adds to the (PCcarbeneP)-IrCl complexes 3(R) (R = Pr-i, Bu-t). Aryl, amido, and phenoxy derivatives are available from the chlorides via salt metathesis. These compounds add H-2 and eliminate H-X; the iridium compound is trapped as a PCalkylP iridium polyhydride.
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