期刊
ORGANOMETALLICS
卷 31, 期 15, 页码 5606-5614出版社
AMER CHEMICAL SOC
DOI: 10.1021/om300569w
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资金
- MEC of Spain [CTQ2011-24055/BQU]
- Bancaixa [P1.1B2010-02, P1.1B2011-22]
- Ministerio de Economia y Competitividad
A series of homo- and hetero-dimetallic complexes of Ir, Rh, and Pd have been obtained using our previously reported Y-shaped tris-NHC ligand. The new complexes can be obtained through the isolation of the corresponding monometallic intermediates (in which the ligand always coordinates in a chelating form) or by a one-pot stepwise synthetic protocol that avoids the isolation of the intermediate. The catalytic properties of the Ir-Pd complexes have been explored in two tandem processes: dehalogenation/transfer hydrogenation of haloacetophenones and Suzuki-coupling/transfer hydrogenation of p-bromoacetophenone. These two complexes have been also tested in two model reactions typically catalyzed by iridium (cyclization of 2-aminophenyl ethyl alcohol to yield indole) and palladium (acylation of bromobenzene with n-hexanal).
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