期刊
ORGANOMETALLICS
卷 31, 期 11, 页码 4114-4117出版社
AMER CHEMICAL SOC
DOI: 10.1021/om300348e
关键词
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资金
- Japan Society of the Promotion of Science (JSPS)
- Waseda University [2011A-896]
- Grants-in-Aid for Scientific Research [23850015] Funding Source: KAKEN
[Ir(cod)(2)]BARF [BARF = tetrakis(3,5-trifluoromethylphenyl)borate] catalyzed the directed alkenylation and alkylation of ferrocenes to form a variety of tri- and disubstituted ferrocenes. Mechanistic investigation revealed several putative intermediates along with the importance of COD (1,5-cyclooctadiene), as a diene ligand, and a possible catalyst deactivation pathway. On the basis of the mechanistic investigation, catalytic activity was further improved.
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