期刊
ORGANOMETALLICS
卷 31, 期 17, 页码 6496-6499出版社
AMER CHEMICAL SOC
DOI: 10.1021/om300413n
关键词
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资金
- Grant Agency of the Czech Republic [GACR 104/09/1497, P106/12/1276]
- Institute of Microbiology [RVO: 61388971]
Asymmetric transfer hydrogenation of the acyclic imine acetophenone N-benzylimine was studied by means of computational chemistry. Calculated transition states offer an explanation of why this prochiral imine leads to the delivery of (S)-amine (when using (S,S)-TsDPEN ligand) rather than (R)-amine, which is common for endocyclic imines (e.g., substituted 3,4-dihydroisoquinolines or 3,4-dihydro-beta-carbolines). This study extends our previous investigation of the so-called ionic mechanism.
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