期刊
ORGANOMETALLICS
卷 31, 期 4, 页码 1335-1340出版社
AMER CHEMICAL SOC
DOI: 10.1021/om200873j
关键词
-
资金
- 973 Program [2012CB821602]
- NSFC [20902100, 20832008, 21172242]
- SIOC
We report a Pd-catalyzed aerobic dehydrogenative cross-coupling of polyfluoroarenes with thiophenes via 2-fold C-H functionalization. The advantages of this reaction are its high reaction efficiency, excellent functional group compatibility, and use of molecular O-2 as terminal oxidant. This reaction provides a useful and facile protocol for the preparation of polyfluoroarene thiophene structure of interest in functional materials. Mechanistic studies revealed that the reaction is initiated by the C-H bond cleavage of polyfluoroarenes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据