期刊
ORGANOMETALLICS
卷 31, 期 7, 页码 2597-2605出版社
AMER CHEMICAL SOC
DOI: 10.1021/om200397t
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资金
- Ministerio de Ciencia e Innovacion [CTQ2010-20500]
- Departamento de Ciencia, Tecnologia y Universidad del Gobierno de Aragon [E77]
- Austrian Science Fund (FWF) [E77] Funding Source: Austrian Science Fund (FWF)
In this paper we describe the reactivity of the gold acetylide derivatives [Au(C CR)(PPh3)] (R = Ph, 2-py). Reactions of these complexes with fragments of the type [M(PPh3)(2)](+) (M = Au, Ag, Cu) afford a series of novel discrete molecules stabilized not only by interactions with the triple bond but also by the formation of strong metal-gold interactions. The crystal structures of the gold-gold and gold-silver species confirm their similar behavior, while X-ray diffraction establishes a different arrangement for the copper complex with pyridine acetylide as a consequence of the coordination of this metal center to the nitrogen atom of pyridine and to the carbons of the alkyne. The luminescent properties of the complexes were also studied.
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