期刊
ORGANOMETALLICS
卷 30, 期 20, 页码 5304-5313出版社
AMER CHEMICAL SOC
DOI: 10.1021/om200650x
关键词
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资金
- NSF [CHE-1112133, CHE-0924410]
- NIH [R01 GM 68825]
- DOE [DE-FG02-09ER16069]
- RHODIA Inc.
- Direct For Mathematical & Physical Scien [0924410] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1316956] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1112133] Funding Source: National Science Foundation
- Division Of Chemistry [0924410] Funding Source: National Science Foundation
This personal account summarizes our work, beginning with the discovery of the first stable carbene in 1988 up until the recent isolation of mesoionic carbenes. It explains why we have moved our focus from acyclic to cyclic carbenes and shows that these stable species are not limited to the role of ligand for transition metals but that they are also powerful agents for the activation of small molecules, and for the stabilization of highly reactive diamagnetic and paramagnetic species.
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