期刊
ORGANOMETALLICS
卷 30, 期 5, 页码 921-924出版社
AMER CHEMICAL SOC
DOI: 10.1021/om1011006
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资金
- National Science Foundation [CHE 0956021]
- Deutscher Akademischer Austauschdienst (DAAD)
- U.S. Department of Education
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0956021] Funding Source: National Science Foundation
3,3'-Silylated binaphtholate tantalum and niobium complexes were shown to be efficient catalysts for the asymmetric hydroaminoalkylation of N-methylaniline derivatives and N-benzylmethylamine with simple alkenes in enantioselectivities of up to 80% ee. No hydroaminoalkylation was observed with aminoalkenes; rather, exclusive asymmetric hydroamination/cyclization took place in up to 81% ee.
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