4.5 Article

Polymerization of Racemic β-Butyrolactone Using Gold Catalysts: A Simple Access to Biodegradable Polymers

期刊

ORGANOMETALLICS
卷 30, 期 10, 页码 2650-2653

出版社

AMER CHEMICAL SOC
DOI: 10.1021/om200271q

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资金

  1. ENSCP
  2. CNRS
  3. French Ministry of Higher Education and Research
  4. ERC
  5. EPSRC
  6. Royal Society
  7. EPSRC [EP/H015418/1] Funding Source: UKRI
  8. Engineering and Physical Sciences Research Council [EP/H015418/1] Funding Source: researchfish

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Novel gold(I) complexes containing N-heterocyclic carbene ligands have been synthesized and fully characterized. The resulting mononuclear gold complexes act as active initiators in the polymerization of rac-beta-butyrolactone under solvent-free conditions to provide the corresponding biodegradable poly(3-hydroxybutyrate).

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