4.5 Article

(N-Heterocyclic Carbene)PdCl2(TEA) Complexes: Studies on the Effect of the Throw-Away Ligand in Catalytic Activity

期刊

ORGANOMETALLICS
卷 30, 期 18, 页码 5052-5056

出版社

AMER CHEMICAL SOC
DOI: 10.1021/om200699p

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资金

  1. National Science Foundation [CHE-0924324]
  2. NWDA
  3. EPSRC
  4. Division Of Chemistry
  5. Direct For Mathematical & Physical Scien [0924324] Funding Source: National Science Foundation
  6. Engineering and Physical Sciences Research Council [EP/H004408/1] Funding Source: researchfish
  7. EPSRC [EP/H004408/1] Funding Source: UKRI

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The synthesis and characterization of a series of (N-heterocyclic carbene)PdCl2(TEA) (TEA = triethylamine) complexes are presented. A comparison of their activity in the Suzuki-Miyaura and Buchwald-Hartwig reactions with similar (N-heterocyclic carbene)Pd(II) complexes is also presented.

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