期刊
ORGANOMETALLICS
卷 30, 期 15, 页码 4032-4038出版社
AMER CHEMICAL SOC
DOI: 10.1021/om2002987
关键词
-
资金
- NSFC [91027005, 20902027]
- Shanghai Pujiang Program [09PJ1404100]
- Shanghai Shuguang Program [09SG25]
- SMEC [10ZZ32]
- RFDP of Higher Education of China [20100076110004]
- Fundamental Research Funds for the Central Universities
A new family of platinum acetylide derivatives containing iptycene building blocks end-capped with 3,4,5-tris(alkoxy)phenyl substituents has been successfully synthesized. The structure of the newly designed complexes was characterized by multinuclear NMR ((1)H, (31)P, and (13)C) and mass spectroscopy and elemental analysis. Unexpectedly, all compounds presented good gel formation properties in some common organic solvents. The morphology of the xerogels was investigated by scanning electron microscopy (SEM). An investigation using electronic absorption and emission spectra was carried out to study the spectroscopic properties of all organometallic complexes in both solution and gel states.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据