4.5 Article

Disambiguation of Metal and Bronsted Acid Catalyzed Pathways for Hydroarylation with Platinum(II) Catalysts

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ORGANOMETALLICS
卷 30, 期 6, 页码 1295-1298

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AMER CHEMICAL SOC
DOI: 10.1021/om2000458

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  1. Office of Energy Research, Office of Basic Energy Sciences, Chemical Sciences Division, of the U.S. Department of Energy [DE-AC02-05CH11231]

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The hydroarylation of unactivated olefins effected by Pt(II) precatalysts was found to proceed through the in situ production of protic acid followed by a Friedel Crafts mechanism. The reaction was investigated using the hindered base 2,6-di-tert-butyl-4-methylpyridine and a variety of substrates.

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