期刊
ORGANOMETALLICS
卷 30, 期 15, 页码 3915-3918出版社
AMER CHEMICAL SOC
DOI: 10.1021/om200363z
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资金
- University of Toledo
A series of new homoleptic rare-earth-metal complexes as synthesized using salt metathesis reactions between LnCl(3) and alpha-K(DMBA) (Ln = La (1), Ce (2), Pr (3), Nd (4), Sm (5), Gd (6), Y (7); DMBA = N,N-dimethylbenzylamine). All seven complexes were found to be free of coordinating solvent, and no formation of any -ate species was observed. The ligands in complexes 1-7 displayed eta(4) coordination to the metal center. Subsequently, the reactivity of 1 and 7 was investigated via various protonolysis reactions using silylamines, anilines, and phenols to generate a diverse array of other homoleptic lanthanide complexes.
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