期刊
ORGANOMETALLICS
卷 30, 期 9, 页码 2628-2631出版社
AMER CHEMICAL SOC
DOI: 10.1021/om200069t
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资金
- Academy of Finland
- Deutscher Akademischer Austauschdienst (DAAD)
- Deutsche Forschungsgemeinschaft (DFG) [Gu 415/12-2]
- COST [CM0802]
A palladium 1,2-ethylene-bisphosphine complex prepared by diphosphination of acrylonitrile and subsequent complexation undergoes facile and reversible C deprotonation at a backbone carbon atom. The 1,2-diphosphinoethanide complex that formed was characterized by spectroscopic data and a single-crystal X-ray diffraction study. The reaction may explain the previously observed configurational lability of coordinated 1, 2-bisphosphine ligands with electron-withdrawing substituents.
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