期刊
ORGANOMETALLICS
卷 30, 期 7, 页码 1772-1775出版社
AMER CHEMICAL SOC
DOI: 10.1021/om2000585
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资金
- EPSRC [EP/E052789/1]
- University College London
- Engineering and Physical Sciences Research Council [EP/E052789/1] Funding Source: researchfish
- EPSRC [EP/E052789/1] Funding Source: UKRI
The Pd-mediated oxidation of unsaturated thioacetals gives either allyl or vinyl esters, depending on the substrate structure. We report the characterization of a range of sulfur-stabilized palladium intermediates via a combined computational and experimental NMR approach, demonstrating that the oxidation proceeds via two divergent reaction mechanisms. We were also able to synthesize an unusual sigma-bound Pd complex, via acetoxypalladation of an unsaturated dithiane, which was characterized by X-ray crystallography.
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