期刊
ORGANOMETALLICS
卷 29, 期 10, 页码 2199-2202出版社
AMER CHEMICAL SOC
DOI: 10.1021/om100060y
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资金
- KAUST (King Abdullah University of Science and Technology)
The nickel-induced coupling of ethylene and CO2 represents a promising pathway toward acrylates. To overcome the high bond dissociation energies of the M-O moieties, we worked out an in situ methylation of nickelalactones to realize the beta-hydirde elimination and the liberation of the acrylate species.
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