期刊
ORGANOMETALLICS
卷 29, 期 17, 页码 3966-3972出版社
AMER CHEMICAL SOC
DOI: 10.1021/om100733n
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资金
- EPSRC
- ERC
- Royal Society
- Engineering and Physical Sciences Research Council [EP/H015418/1] Funding Source: researchfish
- EPSRC [EP/H015418/1] Funding Source: UKRI
The novel 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (hydroxy) copper ([Cu(IPr)(OH)]) exhibits a versatile capacity to activate numerous X-H bonds including all major hybridizations of C-H (i.e., sp, sp(2), sp(3)), N-H, P-H, O-H,S-H, and one example of M-H (M = Mo) bonds. This reactivity also includes the cleavage of the Si-N and Si-C bonds to form unprecedented Cu-centered complexes.
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