期刊
ORGANOMETALLICS
卷 29, 期 4, 页码 928-933出版社
AMER CHEMICAL SOC
DOI: 10.1021/om900975a
关键词
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资金
- Shanghai Municipal Committee of Science and Technology [06XD14005, 08dj1400100-2]
- National Basic Research Program of China [973-2009CB825300]
- National Natural Science Foundation of China [20472096, 20872162, 20672127, 20821002, 20732008]
Bis(NHC)-Pd(II) complexes derived from 1,1'-binaphthyl-2,2'-diamine (BINAM) were successfully first used to catalyze the dioxygenation of alkenes under mild conditions tolerant of air and moisture. Cationic NHC-Pd2+ diaquo complex le showed the highest catalytic activity to give 1,2-dioxygenation products with good syn-diastercoselectivity for 1,2-disubstituted alkenes.
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