期刊
ORGANOMETALLICS
卷 29, 期 4, 页码 951-956出版社
AMER CHEMICAL SOC
DOI: 10.1021/om901026m
关键词
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资金
- MICINN [CTQ2007-67411/BQU, CTQ2007-60745/BQU]
- Consolider Ingenio 2010 [CSD2006-0003]
- Juan de la Cierva
- Juan de la Cierva [2009 SGR 47]
- Junta de Castilla y Leon [GR169]
- ICIQ Foundation
Complexes [AuCl{C(NHR)(NHR')}] and [AuCl{C(NHR)(NEt2)}] (R =Bu-t, p-Tol, Xylyl, p-C6H4-COOH, p-C6H4COOEt, R' = Me, Bu-n, Pr-i, (n)heptyl, p-Tol) have been prepared by reaction of the corresponding isocyanogold complexes [AuCl(CNR)] with either primary amines or diethylamine. All the prepared carbenes are reactive and highly selective catalysts for skeletal rearrangement, methoxycyclization of 1,6-enynes, and other mechanistically related gold-catalyzed transformations. Overall, these easily accessible nitrogen acyclic carbene (NAC) gold complexes were not second to NHC complexes and were advantageous to obtain different products.
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