期刊
ORGANOMETALLICS
卷 29, 期 2, 页码 290-293出版社
AMER CHEMICAL SOC
DOI: 10.1021/om9010406
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资金
- National Science Council (Taiwan, ROC)
- National Dong Hwa University
The methylenebis(N-alkylimidazolium) halides are converted to dialkylbiimidazoles by cuprous oxide wit concurrent C-N bond cleavage and C-C bond formation. This unusual C-N bond cleavage is proposed to involve a Cu(I)-NHC (N-heterocyclic carbene) complex. The reaction is unique, as it involves C-H bond activation, C-N bond cleavage, and C-C bond formation.
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