期刊
ORGANOMETALLICS
卷 29, 期 22, 页码 5773-5775出版社
AMER CHEMICAL SOC
DOI: 10.1021/om1009186
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资金
- Japan Society for the Promotion of Science [22245014, 20750073]
- G-COE in chemistry (Nagoya)
- Grants-in-Aid for Scientific Research [20750073, 22245014] Funding Source: KAKEN
New chiral pincer iron complexes having bis(oxazolinyl)phenyl ligands have been synthesized by oxidative addition of Fe-2(CO)(9) to 2-bromo-substituted ligands. This chiral pincer iron complex can catalyze the asymmetric hydrosilylation of simple aromatic ketones to give the corresponding alcohols.
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