A side-product that accompanies the synthesis of the widely utilized starting material TpRu(PPh3)(2)Cl (Tp = hydridotris(pyrazolyl)borate) has been identified as the complex (Cl)TpRu(PPh3)(2)H ((Cl)Tp = chlorotris(pyrazolyl)borate), which provides a rare example (if a boron-halogenated pyrazolylborate ligand. The reaction of (Cl)TpRu(PPh3)(2)H with dichloromethane or chloroform quantitatively produce (Cl)TpRu(PPh3)(2)Cl.
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