期刊
ORGANOMETALLICS
卷 28, 期 9, 页码 2920-2926出版社
AMER CHEMICAL SOC
DOI: 10.1021/om9001186
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资金
- Scientific Research for Young Scientists [19675002]
- Scientific Research on Priority Areas [18066003]
Ruthenium-catalyzed enantioselective cyclization of propargylic alcohols bearing a thiophene moiety affords the corresponding propargylated thiophenes in good to high yields with a high enantioselectivity (up to 97% ee). This catalytic reaction is proposed to proceed via chiral ruthenium-allenylidene complexes as key intermediates.
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