4.5 Article

Photoactivation of Ruthenium Olefin Metathesis Initiators

期刊

ORGANOMETALLICS
卷 28, 期 16, 页码 4652-4655

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AMER CHEMICAL SOC
DOI: 10.1021/om9004302

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  1. The Edmond Safra Foundation
  2. Minerva Foundation

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UV irradiation of latent sulfur-chelated ruthenium olefin metathesis precatalysts produced a cis-dichloro-trans-dichloro photoisomerization. The enhanced activity of the trans isomer, when aromatic substituents were attached to the sulfur chelating atom, induced several metathesis reactions, including ROMP, at room temperature.

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