4.5 Article

A General Fluorescence Resonance Energy Transfer (FRET) Method for Observation and Quantification of Organometallic Complexes under Reaction Conditions

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ORGANOMETALLICS
卷 28, 期 16, 页码 4643-4645

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AMER CHEMICAL SOC
DOI: 10.1021/om900629s

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  1. U.S. Department of Energy
  2. Office of Basic Energy Sciences [DE-FG02-08ER1534]

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A two-fluorophore FRET system provided a more general approach than previously described fluorescence techniques to observing and quantifying organometallic complexes under reaction conditions. Over the concentration range of 3 x 10(-7) to 5 x 10(-6) M, this method provided quantification with faster time resolution and greater sensitivity, than is possible with NMR spectroscopy.

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