期刊
ORGANOMETALLICS
卷 28, 期 15, 页码 4624-4627出版社
AMER CHEMICAL SOC
DOI: 10.1021/om9003434
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资金
- KOSEF [(R01-2006-000-10696-0)]
- Korean Ministry of Education and Human Resources through KRF [(BK21 program)]
- National Research Foundation of Korea [R01-2006-000-10696-0] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Iodide-bridged diruthenium complexes [(n(5) -2.5-R-2-3.4-Ph2C4COH) (CO)(2) Ru-(mu-I)-Ru(CO)(2)(n(4)-2.5-R-2-3.4-Ph2C4CO)] (6a, R=ph; 6b, R=Me) were formed from the reaction of (n(5-)2.5-3.4-Ph2C4COH)(CO)(2) RuI (2c, R=Ph;2d, R=Me) with [(2.5-R(2-)3.4-Ph2C4CO)(CO)(2)Ru](2) (7a, R=Ph; 7b, R=Me). The complexes exhibited a high catalytic activity for the oxidation of alcohols with silver oxide at room temperature.
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