4.5 Article

1,3-Dinitrone Pincer Complexes of Palladium and Nickel: Synthesis, Structural Characterizations, and Catalysis

期刊

ORGANOMETALLICS
卷 28, 期 11, 页码 3233-3238

出版社

AMER CHEMICAL SOC
DOI: 10.1021/om900009h

关键词

-

资金

  1. School of Physical and Mathematical Sciences
  2. Nanyang Technological University

向作者/读者索取更多资源

Neutral and cationic Pd(II) and Ni(II) OCO-type pincer complexes have been synthesized from the metalation of 1,3-dinitrones via C-H or C-Br bond activation using Pd(0), Pd(II), and Ni(0) starting materials. In each complex, the two six-membered metallacycles are non-coplanar and atropisomerization proceeds with a low barrier. Palladium dinitrone complexes have been shown as active catalysts for Heck couplings and the related Ni complex for Kumada reactions with turnover numbers up to 950 000.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.5
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据