期刊
ORGANOMETALLICS
卷 28, 期 9, 页码 2693-2700出版社
AMER CHEMICAL SOC
DOI: 10.1021/om801183g
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资金
- Polish Ministry of Science and Higher Education [N204157636, N20403302 33]
- Foundation for Polish Science
- European Regional Development Fund in the Sectoral Operational Programme [WKP_1/1.4.3./1/2004/72/72/165/2005/U]
New ruthenium olefin metathesis initiators bearing sulfoxide moieties are described. The complexes were synthesized by the reaction of indenylidene ruthenium complexes Ind-II and Ind-II' with different (2-vinyl)phenyl sulfoxides. These compounds show no catalytic activity at room temperature, but exhibit increased activity at elevated temperature. Preliminary studies on the influence of electronic and steric factors on the catalytic activity are presented.
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