期刊
ORGANOMETALLICS
卷 28, 期 2, 页码 390-393出版社
AMER CHEMICAL SOC
DOI: 10.1021/om801042b
关键词
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资金
- MEXT [16750073, 18065017]
- Tokyo Institute of Technology
- Grants-in-Aid for Scientific Research [16750073, 18065017] Funding Source: KAKEN
A variety of protic 2-(tertiary phosphino)-1-amines (R2PCH2CHR'NHR '', P-NH) have been prepared from 2-ox-azolidinones and secondary phosphines using a newly developed acid-promoted decarboxylative C-P bond formation reaction. Treatment of the resulting chiral P-NH compounds with Cp*RuCl(isoprene) in CH2Cl2 smoothly furnished chiral Cp*RuCl(P-NH) complexes with a typical three-legged piano-stool structure, which prove to be excellent catalyst precursors for asymmetric reactions, including the isomerization of allylic alcohols and hydrogenation of imides.
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