4.5 Article

Isolation and Characterization of a Nucleophilic Allylic Indium Reagent

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ORGANOMETALLICS
卷 28, 期 7, 页码 1998-2000

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AMER CHEMICAL SOC
DOI: 10.1021/om900096r

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  1. Chemistry of Concerto Catalysis [18065015, 20036036]
  2. Synergistic Effects for Creation of Functional Molecules [19550038]
  3. Ministry of Education, Culture, Sports, Science and Technology of Japan

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Transmetalation between allylic stannanes and indium halides gave allylic indium dihalides. The bond length of In-C is 2.172 angstrom, which is close to the reported average indium-carbon bond length. The isolated allylic indium dibromide with two phthalan ligands showed nucleophilicity for a carbonyl compound.

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