期刊
ORGANOMETALLICS
卷 27, 期 21, 页码 5733-5736出版社
AMER CHEMICAL SOC
DOI: 10.1021/om800728m
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资金
- CNRS
- Ministry of Science and Information Societies Technologies of Poland [3TO 9A 158 29]
- LEA (Laboratoire Europeen Associe Toulouse Lodz)
A straightforward and efficient synthetic route to thiazolyl phosphines is reported. Moreover, the first application of these molecules in catalysis is described. These phosphines are excellent ligands in the copper-catalyzed arylation and vinylation of nucleophiles. The reactions could be performed in acetonitrile and various mixed aqueous/organic solvents and even in pure water in the presence of a phase transfer catalyst. In each case, coupling products are obtained with high yields at very mild temperatures.
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