期刊
ORGANOMETALLICS
卷 27, 期 21, 页码 5521-5524出版社
AMER CHEMICAL SOC
DOI: 10.1021/om800644m
关键词
-
资金
- University of California Riverside
- CNRS
- Donors of the American Chemical Society Petroleum Research Fund [44734-AC1]
- National Science Foundation [CHE-0719039]
A 2-terthienylphospholide can be prepared from a 1-terthienylphosphole by reaction with tBuOK in diglyme at 150 degrees C. This phospholide is then transformed into the corresponding 1-methyl-2-terthienylphosphole-borane. This borane complex fluoresces at 5 10 nm in CH2Cl2 with a quantum yield of 0.17. The excited-state displays a significant charge transfer between the terthienyl substituent and the phosphole ring as shown by the shift of the emission to lower energies upon increasing the polarity of the solvent.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据