期刊
ORGANIC LETTERS
卷 20, 期 20, 页码 6573-6577出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02915
关键词
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资金
- National Natural Science Foundation of China [21402126]
- Natural Science Foundation of Liaoning Province [20180550882]
- Basic Scientific Project of Universities in Liaoning Province [LFW201701]
- Program for Young Creative Talents in Shenyang City [RC170189]
- Engineering Technology Research Centre of Catalysis for Energy and Environment-Major Platform for Science and Technology of the Universities in Liaoning Province
A controllable Rh(III)-catalyzed C-H arylation and dealcoholization of benzimidates with arylboronic esters was developed, delivering various biphenyl-2-carbonitriles and biphenyl-2-carbimidates by simply tuning the reaction conditions. This approach features high efficiency, good functional group tolerance, and easy operation. It also provides an alternative pathway to thoroughly exploit the directing group in transition-metal-catalyzed C-H activations.
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