期刊
ORGANIC LETTERS
卷 20, 期 19, 页码 6306-6309出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02821
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资金
- National Natural Science Foundation of China [31670355]
- Natural Science Foundation for Distinguished Young Scholars of Shandong Province [JQ201712]
- Open Fund of Key Laboratory of Experimental Marine Biology, the CAS [KF2017NO4]
- Youth Innovation Promotion Association of the CAS [2013138]
- Yantai Institute of Coastal Zone Research, the CAS [Y755031012]
Tricholumin A (1) with an unprecedented carbon skeleton was isolated from the fungus Trichoderma asperellum cf44-2, an endophyte from the marine brown alga Sargassum sp. Its structure and relative configuration were identified by extensive 1D/2D NMR and mass spectrometric data, and the absolute configuration was assigned by X-ray diffraction and ECD calculations. Compound 1 represents a highly transformed ergosterol derivative, and it exhibited inhibition of some pathogenic microbes and marine phytoplankton species.
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