期刊
ORGANIC LETTERS
卷 20, 期 18, 页码 5866-5871出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02538
关键词
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资金
- National Natural Science Foundation of China [21672121, 21871160]
- Thousand Plan Youth Program of China
- Tsinghua University
- Bayer
- Fellowship of Tsinghua-Peking Centre for Life Sciences (CLS)
The N-heterocyclic carbene (NHC)-catalyzed enantioselective kinetic resolution of anilides (a kind of hemiaminals) is reported. Upon exposure to the reaction in the presence of an NHC precatalyst and base, catalytic C-O bond formation occurs, providing axially chiral isoindolinones in high yields with excellent enantioselectivities.
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