期刊
ORGANIC LETTERS
卷 20, 期 16, 页码 4815-4818出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01969
关键词
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资金
- National Natural Science Foundation of China [81672952, 81430060]
- Guangdong Science and Technology Program [2017A020215198]
- Guangzhou Science and Technology Program [201807010041]
A diverse set of novel heterocyclic iodoniums was synthesized for the first time. The reactions of these unique iodoniums with environmentally benign water as the oxygen source provided structurally complex oxygen-incorporated heteropolycycles that are essential motifs in natural products and biologically active compounds. The transformation only required low-cost copper acetate. Further derivatization of the obtained polycycles expanded the structural diversity, which is important in the building of chemical libraries for drug discovery.
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