期刊
ORGANIC LETTERS
卷 20, 期 17, 页码 5389-5392出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02305
关键词
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资金
- Mitsui Chemicals Award in Synthetic Organic Chemistry, Japan
- UBE Industries Foundation award
- Kanazawa University SAKIGAKE Project
A concise method to directly generate benzyl radicals from benzyl alcohol derivatives has been developed. The simple and inexpensive combination of TiCl4(collidine) (collidine = 2,4,6-collidine) and manganese powder afforded a low-valent titanium reagent, which facilitated homolytic cleavage of benzylic C-OH bonds. The application to radical conjugate addition reactions demonstrated the broad scope of this method. The reaction of various benzyl alcohol derivatives with electron deficient alkenes furnished the corresponding radical adducts.
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