4.8 Article

Rhodium(III)-Catalyzed Meta-Selective C-H Alkenylation of Phenol Derivatives

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ORGANIC LETTERS
卷 20, 期 17, 页码 5126-5129

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AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b01995

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  1. National Nature Science Foundation of China [21101085]
  2. Program for Liaoning Innovative Talents in University [LR2017021]

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Rhodium(III)-catalyzed remote meta-selective C-H alkenylation of phenol derivatives has been developed using a traceless organosilicon template as the directing group. This transformation proceeds smoothly with good yields and high meta-selectivities toward a series of phenol and alkene substrates. In addition, this protocol provides an effective strategy for late-stage transformations of various meta-alkenylated aromatic compounds.

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