期刊
ORGANIC LETTERS
卷 20, 期 17, 页码 5402-5405出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02310
关键词
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资金
- National Natural Science Foundation of China [21572051, 21602057]
- Opening Fund of Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education of China), Hunan Normal University [KLCBTCMR201707, KLCBTCMR201708]
A novel tandem intermolecular decarboxylative coupling reaction of o-bromobenzoic acids and aryl iodides has been developed. The method affords a range of unsymmetrically triphenylenes and displays unique regioselectivity and broad substrate scope. Mechanistically, palladium/norbornene-catalyzed C-H activation and subsequent double decarboxylative coupling reactions were involved. Moreover, the triphenylenes can also be synthesized from 2-iodobiphenyls and o-bromobenzoic acids under norbornene-free conditions.
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