期刊
ORGANIC LETTERS
卷 20, 期 19, 页码 6140-6143出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02613
关键词
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资金
- National Key Research and Development Program of China [2016YFA0602900]
- Guangdong Province Science Foundation [2017B090903003]
- Guangdong Natural Science Foundation [2018B030308007]
Zn(OAc)(2)-catalyzed highly regioselective carbonylacetylation of indoles and pyrroles with alpha-diazoketones has been developed. This transformation involves a combination of Wolff rearrangement/cross-coupling relay and provides an efficient approach to versatile 3-carbonylacetylindoles and 2-carbonylacetylpyrroles with a broad range of functional group tolerance.
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