期刊
ORGANIC LETTERS
卷 20, 期 17, 页码 5282-5285出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02225
关键词
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资金
- School of Chemistry, Cardiff University
- EPSRC [EP/M50631X/1]
- EPSRC UK National Mass Spectrometry Facility at Swansea University
N-Allenyl cyanamides have been accessed via a one-pot deoxycyanamidation-isomerization approach using propargyl alcohol and N-cyano-N-phenyl-p-methylbenzene-sulfonamide. The utility of this novel class of allenamide was explored through derivatization, with hydroarylation, hydroamination, and cycloaddition protocols employed to access an array of cyanamide products that would be challenging to access using existing methods.
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