期刊
ORGANIC LETTERS
卷 16, 期 4, 页码 1128-1131出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol403739w
关键词
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资金
- National Science Foundation of China [21102138, J1030412]
- Chinese Academy of Sciences
- Ministry of Education [SRFDP 20123402110040]
- University of Science and Technology of China (USTC)
The first example of silver-mediated oxidative aryltrifluoromethylthiolation of activated alkenes to produce valuable trifluoromethylthiole-containing oxindoles was developed. Mechanistic investigations indicated that this novel transformation proceeded through a unique F3CS center dot radical addition path, thus providing a practical and easy-handling method to generate a F3CS center dot radical in the laboratory.
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