期刊
ORGANIC LETTERS
卷 16, 期 4, 页码 1188-1191出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol5000605
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资金
- MEXT
- JSPS
- JST, Japan
- Grants-in-Aid for Scientific Research [25288048] Funding Source: KAKEN
The rhodium-catalyzed ortho-alkenylation of phenyl sulfoxides using alkenes or alkynes as substituent sources proceeds efficiently through sulfoxide group directed C-H bond cleavage to produce the corresponding o-alkenylphenyl sulfoxides. The products readily undergo interrupted Pumerer cyclization as well as reduction to afford benzothiophenes and o-alkenylphenyl sulfides.
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