期刊
ORGANIC LETTERS
卷 16, 期 6, 页码 1586-1589出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol500186j
关键词
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资金
- Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- NSFC
Rhodium(III)-catalyzed arylation of arenes bearing a chelating group has been realized via a redox-economy process using 4-hydroxycyclohexa-2,5-dienones as the arylating reagents, leading to the synthesis of 3-arylated phenols. This redox-neutral process proceeds via a C-H activation pathway with rearomatization being the driving force.
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