期刊
ORGANIC LETTERS
卷 16, 期 11, 页码 2892-2895出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol501037j
关键词
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资金
- MEXT
- JSPS, Japan
- Grants-in-Aid for Scientific Research [25620084] Funding Source: KAKEN
A Cu-catalyzed intramolecular C-H amination for the synthesis of carbazoles has been developed. The key to success is the installation of the picolinamide-based directing group, which is spontaneously removed after the coupling event. The Cu catalysis proceeded smoothly under Pd- and I(III)-free conditions, and its mild oxidation aptitude enables the rapid and concise construction of heteroatom-incorporated carbazole core pi-systems.
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