4.8 Article

Palladium-Catalyzed Direct Ortho-Nitration of Azoarenes Using NO2 as Nitro Source

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ORGANIC LETTERS
卷 16, 期 17, 页码 4540-4542

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AMER CHEMICAL SOC
DOI: 10.1021/ol502090n

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  1. National Natural Science Foundation of China [21272117, 20972068]
  2. Priority Academic Program Development of Jiangsu Higher Education Institutions

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A palladium-catalyzed direct ortho-nitration reaction of azoarenes was developed in which NO2 was used as both nitro source and oxidant for the first time. The nitration products were converted into o-aminoazoarenes or benzotriazole derivatives by a simple reduction.

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